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Synthesis and Characterization of Heterobimetallic Iridium-Aluminum and Rhodium-Aluminum Complexes.
Brewster, Timothy P; Nguyen, Tan H; Li, Zhongjing; Eckenhoff, William T; Schley, Nathan D; DeYonker, Nathan J.
Afiliação
  • Brewster TP; Department of Chemistry, The University of Memphis , 3744 Walker Avenue, Smith Chemistry Building, Memphis, Tennessee 38152, United States.
  • Nguyen TH; Department of Chemistry, The University of Memphis , 3744 Walker Avenue, Smith Chemistry Building, Memphis, Tennessee 38152, United States.
  • Li Z; Department of Chemistry, The University of Memphis , 3744 Walker Avenue, Smith Chemistry Building, Memphis, Tennessee 38152, United States.
  • Eckenhoff WT; Department of Chemistry, Rhodes College , 2000 N. Parkway, Memphis, Tennessee 38112, United States.
  • Schley ND; Department of Chemistry, Vanderbilt University , Nashville, Tennessee 37235, United States.
  • DeYonker NJ; Department of Chemistry, The University of Memphis , 3744 Walker Avenue, Smith Chemistry Building, Memphis, Tennessee 38152, United States.
Inorg Chem ; 57(3): 1148-1157, 2018 Feb 05.
Article em En | MEDLINE | ID: mdl-29356511
We demonstrate the synthesis and characterization of a new class of late-transition-metal-aluminum heterobimetallic complexes via a novel synthetic pathway. Complexes of this type are exceedingly rare. Joint experimental and theoretical data sheds light on the electronic effect of ligands containing aluminum moieties on late-transition-metal complexes.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article