Ligand metathesis as rational strategy for the synthesis of cubane-type heteroleptic iron-sulfur clusters relevant to the FeMo cofactor.

Xu, Gan; Wang, Zheng; Ling, Rong; Zhou, Jie; Chen, Xu-Dong; Holm, Richard H

Xu, Gan; Wang, Zheng; Ling, Rong; Zhou, Jie; Chen, Xu-Dong; Holm, Richard H.

Afiliação

Xu G; Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China.
Wang Z; Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China.
Ling R; Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China.
Zhou J; Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China.
Chen XD; Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China; xdchen@njnu.edu.cn holm@chemistry.harvard.edu.
Holm RH; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138.

Proc Natl Acad Sci U S A ; 115(20): 5089-5092, 2018 05 15.

Article em En | MEDLINE | ID: mdl-29654147

Assuntos

Complexos de Coordenação/química; Molibdênio/química; Molibdoferredoxina/química; Enxofre/química; Catálise; Domínio Catalítico; Cristalografia por Raios X; Proteínas Ferro-Enxofre/química; Proteínas Ferro-Enxofre/metabolismo; Ligantes; Modelos Moleculares; Estrutura Molecular; Nitrogenase/química; Nitrogenase/metabolismo; Oxirredução

Palavras-chave

FeMo cofactor; cubane-type clusters; heteroleptic clusters; ligand metathesis; tungstenironsulfur clusters

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Enxofre / Complexos de Coordenação / Molibdênio / Molibdoferredoxina País/Região como assunto: Cuba Idioma: En Ano de publicação: 2018 Tipo de documento: Article

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