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Xylylene Clips for the Topology-Guided Control of the Inclusion and Self-Assembling Properties of Cyclodextrins.
Neva, Tania; Carmona, Thais; Benito, Juan M; Przybylski, Cédric; Ortiz Mellet, Carmen; Mendicuti, Francisco; García Fernández, José M.
Afiliação
  • Neva T; Instituto de Investigaciones Químicas (IIQ) , CSIC-University of Sevilla , Avda. Americo Vespucio 49 , 41092 Sevilla , Spain.
  • Carmona T; Department of Analytical Chemistry, Physical Chemistry and Chemical Engineering, Faculty of Chemistry, Edificio de Farmacia , Campus Universitario Ctra. Madrid-Barcelona , Km 33.600 , 28871 Alcalá de Henares, Madrid , Spain.
  • Benito JM; Instituto de Investigaciones Químicas (IIQ) , CSIC-University of Sevilla , Avda. Americo Vespucio 49 , 41092 Sevilla , Spain.
  • Przybylski C; Institut Parisien de Chimie Moléculaire (IPCM), CNRS UMR 8232 , Sorbonne Université , 4 place Jussieu , 75252 Paris Cedex 05 , France.
  • Ortiz Mellet C; Department of Organic Chemistry, Faculty of Chemistry , University of Sevilla , C/Profesor García González 1 , 41012 Sevilla , Spain.
  • Mendicuti F; Department of Analytical Chemistry, Physical Chemistry and Chemical Engineering, Faculty of Chemistry, Edificio de Farmacia , Campus Universitario Ctra. Madrid-Barcelona , Km 33.600 , 28871 Alcalá de Henares, Madrid , Spain.
  • García Fernández JM; Instituto de Investigaciones Químicas (IIQ) , CSIC-University of Sevilla , Avda. Americo Vespucio 49 , 41092 Sevilla , Spain.
J Org Chem ; 83(10): 5588-5597, 2018 05 18.
Article em En | MEDLINE | ID: mdl-29683327
The topology of ß-cyclodextrin can be molded, from toroidal to ovoid basket-shaped, by the installation of an o- or m-xylylene moiety connecting two consecutive d-glucopyranosyl units through the secondary O-2(I) and O-3(II) positions. This strategy can be exploited advantageously to precast the cavity for preferential inclusion of globular or planar guests as well as to privilege dimeric or monomeric species in water solution.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article