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Loading across the Periodic Table: Introducing 14 Different Metal Ions To Enhance Metal-Organic Framework Performance.
Chen, Shoushun; Lucier, Bryan E G; Luo, Wilson; Xie, Xinkai; Feng, Kun; Chan, Hendrick; Terskikh, Victor V; Sun, Xuhui; Sham, Tsun-Kong; Workentin, Mark S; Huang, Yining.
Afiliação
  • Chen S; Department of Chemistry , University of Western Ontario , London , Ontario N6A 5B7 , Canada.
  • Lucier BEG; Department of Chemistry , University of Western Ontario , London , Ontario N6A 5B7 , Canada.
  • Luo W; Department of Chemistry , University of Western Ontario , London , Ontario N6A 5B7 , Canada.
  • Xie X; Institute of Functional Nano & Soft Materials Laboratory (FUNSOM) & Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices , Soochow University , Jiangsu 215123 , P. R. China.
  • Feng K; Institute of Functional Nano & Soft Materials Laboratory (FUNSOM) & Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices , Soochow University , Jiangsu 215123 , P. R. China.
  • Chan H; Department of Chemistry , University of Western Ontario , London , Ontario N6A 5B7 , Canada.
  • Terskikh VV; Department of Chemistry , University of Ottawa , Ottawa , Ontario K1N 6N5 , Canada.
  • Sun X; Institute of Functional Nano & Soft Materials Laboratory (FUNSOM) & Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices , Soochow University , Jiangsu 215123 , P. R. China.
  • Sham TK; Department of Chemistry , University of Western Ontario , London , Ontario N6A 5B7 , Canada.
  • Workentin MS; Department of Chemistry , University of Western Ontario , London , Ontario N6A 5B7 , Canada.
  • Huang Y; Department of Chemistry , University of Western Ontario , London , Ontario N6A 5B7 , Canada.
ACS Appl Mater Interfaces ; 10(36): 30296-30305, 2018 Sep 12.
Article em En | MEDLINE | ID: mdl-30124282
Loading metal guests within metal-organic frameworks (MOFs) via secondary functional groups is a promising route for introducing or enhancing MOF performance in various applications. In this work, 14 metal ions (Li+, Na+, K+, Mg2+, Ca2+, Ba2+, Zn2+, Co2+, Mn2+, Ag+, Cd2+, La3+, In3+, and Pb2+) have been successfully introduced within the MIL-121 MOF using a cost-efficient route involving free carboxylic groups on the linker. The local and long-range structure of the metal-loaded MOFs is characterized using multinuclear solid-state NMR and X-ray diffraction methods. Li/Mg/Ca-loaded MIL-121 and Ag nanoparticle-loaded MIL-121 exhibit enhanced H2 and CO2 adsorption; Ag nanoparticle-loaded MIL-121 also demonstrates remarkable catalytic activity in the reduction of 4-nitrophenol.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article