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Two-Dimensional Metal-Organic Layers on Carbon Nanotubes to Overcome Conductivity Constraint in Electrocatalysis.
Yang, Ling; Cao, Lingyun; Huang, Ruiyun; Hou, Zhong-Wei; Qian, Xiang-Yang; An, Bing; Xu, Hai-Chao; Lin, Wenbin; Wang, Cheng.
Afiliação
  • Yang L; College of Chemistry and Chemical Engineering, iCHEM, State Key Laboratory of Physical Chemistry of Solid Surface , Xiamen University , Xiamen 361005 , China.
  • Cao L; College of Chemistry and Chemical Engineering, iCHEM, State Key Laboratory of Physical Chemistry of Solid Surface , Xiamen University , Xiamen 361005 , China.
  • Huang R; College of Chemistry and Chemical Engineering, iCHEM, State Key Laboratory of Physical Chemistry of Solid Surface , Xiamen University , Xiamen 361005 , China.
  • Hou ZW; College of Chemistry and Chemical Engineering, iCHEM, State Key Laboratory of Physical Chemistry of Solid Surface , Xiamen University , Xiamen 361005 , China.
  • Qian XY; College of Chemistry and Chemical Engineering, iCHEM, State Key Laboratory of Physical Chemistry of Solid Surface , Xiamen University , Xiamen 361005 , China.
  • An B; College of Chemistry and Chemical Engineering, iCHEM, State Key Laboratory of Physical Chemistry of Solid Surface , Xiamen University , Xiamen 361005 , China.
  • Xu HC; College of Chemistry and Chemical Engineering, iCHEM, State Key Laboratory of Physical Chemistry of Solid Surface , Xiamen University , Xiamen 361005 , China.
  • Lin W; College of Chemistry and Chemical Engineering, iCHEM, State Key Laboratory of Physical Chemistry of Solid Surface , Xiamen University , Xiamen 361005 , China.
  • Wang C; Department of Chemistry , University of Chicago , 929 East 57th Street , Chicago , Illinois 60637 , United States.
ACS Appl Mater Interfaces ; 10(42): 36290-36296, 2018 Oct 24.
Article em En | MEDLINE | ID: mdl-30259735
ABSTRACT
Application of metal-organic frameworks (MOFs) in electrocatalysis is of great interest, but is limited by low electrical conductivities of most MOFs. To overcome this limitation, we constructed a two-dimensional version of MOF-metal-organic layer (MOL) on conductive multiwalled carbon nanotubes (CNTs) via facile solvothermal synthesis. The redox-active MOLs supported on the CNT efficiently catalyze the electrochemical oxidation of alcohols to aldehydes and ketones. Interestingly, this CNT/MOL assembly also endowed the selectivity for primary versus secondary alcohols via well-designed interfacial interactions. This work opens doors toward a variety of designer electrocatalysts built from functional MOFs.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article