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Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis.
Cartier, Alex; Levernier, Etienne; Corcé, Vincent; Fukuyama, Takahide; Dhimane, Anne-Lise; Ollivier, Cyril; Ryu, Ilhyong; Fensterbank, Louis.
Afiliação
  • Cartier A; Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka, 599-8531, Japan.
  • Levernier E; Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, CC 229, 75252, Paris Cedex 05, France.
  • Corcé V; Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, CC 229, 75252, Paris Cedex 05, France.
  • Fukuyama T; Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka, 599-8531, Japan.
  • Dhimane AL; Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, CC 229, 75252, Paris Cedex 05, France.
  • Ollivier C; Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, CC 229, 75252, Paris Cedex 05, France.
  • Ryu I; Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka, 599-8531, Japan.
  • Fensterbank L; Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan.
Angew Chem Int Ed Engl ; 58(6): 1789-1793, 2019 Feb 04.
Article em En | MEDLINE | ID: mdl-30479048
ABSTRACT
Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article