Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis.
Angew Chem Int Ed Engl
; 58(6): 1789-1793, 2019 Feb 04.
Article
em En
| MEDLINE
| ID: mdl-30479048
ABSTRACT
Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2019
Tipo de documento:
Article