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Mononuclear Nickel(II) Complexes with Schiff Base Ligands: Synthesis, Characterization, and Catalytic Activity in Norbornene Polymerization.
Xu, Yi-Mei; Li, Kuan; Wang, Yuhong; Deng, Wei; Yao, Zi-Jian.
Afiliação
  • Xu YM; School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China. 166061228@sit.edu.cn.
  • Li K; School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China. 156061209@sit.edu.cn.
  • Wang Y; School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China. yuhong_wang502@sit.edu.cn.
  • Deng W; School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China. wdeng@sit.edu.cn.
  • Yao ZJ; School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China. zjyao@sit.edu.cn.
Polymers (Basel) ; 9(3)2017 Mar 16.
Article em En | MEDLINE | ID: mdl-30970787
The nickel(II) catalyst has manifested higher catalytic activity compared to that of other late transition metal catalysts for norbornene polymerization. Therefore, several structurally similar trans-nickel(II) compounds of N,O-chelate bidentate ligands were synthesized and characterized. Both the electronic effect and the steric hindrance influence polymerization. The molecular structures of 2, 4 and 5 were further confirmed by single-crystal X-ray diffraction.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article