Applications of Three Dithienylpyrroles-Based Electrochromic Polymers in High-Contrast Electrochromic Devices.
Polymers (Basel)
; 9(3)2017 Mar 22.
Article
em En
| MEDLINE
| ID: mdl-30970793
ABSTRACT
Three dithienylpyrroles (1-(4-(methylthio)phenyl)-2,5-di(thiophen-2-yl)-pyrrole (MPS), 1-(4-methoxyphenyl)-2,5-di(thiophen-2-yl)-pyrrole (MPO), and 4-(2,5-di(thiophen-2-yl)-pyrrol-1-yl)benzonitrile (ANIL)) were synthesized and their corresponding polydithienylpyrroles (PSNS) were electrosynthesized using electrochemical polymerization. Spectroelectrochemical studies indicated that poly(1-(4-(methylthio)phenyl)-2,5-di(thiophen-2-yl)-pyrrole) (PMPS) film was green, dark green, and brown in the neutral, oxidation, and highly oxidized state, respectively. The incorporation of a MPS unit into the PSNS backbone gave rise to a darker color than those of the MPO and ANIL units in the highly oxidized state. The PMPS film showed higher ΔTmax (54.47% at 940 nm) than those of the PMPO (43.87% at 890 nm) and PANIL (44.63% at 950 nm) films in an ionic liquid solution. Electrochromic devices (ECDs) employing PMPS, PMPO, and PANIL as anodic layers and poly(3,4-(2,2-diethypropylenedioxy)thiophene)(PProDOT-Et2) as a cathodic layer were constructed. PMPO/PProDOT-Et2 ECD showed the highest ΔTmax (41.13%) and coloration efficiency (674.67 cm²·C-¹) at 626 nm, whereas PMPS/PProDOT-Et2 ECD displayed satisfactory ΔTmax (32.51%) and coloration efficiency (637.25 cm²·C-¹) at 590 nm. Repeated cyclic voltammograms of PMPS/PProDOT-Et2, PMPO/PProDOT-Et2, and PANIL/PProDOT-Et2 ECDs indicated that ECDs had satisfactory redox stability.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2017
Tipo de documento:
Article