Magnesium-Catalyzed Hydroboration of Terminal and Internal Alkynes.
Angew Chem Int Ed Engl
; 58(21): 7025-7029, 2019 May 20.
Article
em En
| MEDLINE
| ID: mdl-30977970
A magnesium-catalyzed hydroboration of alkynes providing good yields and selectivities for a wide range of terminal and symmetrical and unsymmetrical internal alkynes has been developed. The compatibility with many functional groups makes this magnesium catalyzed procedure attractive for late stage functionalization. Experimental mechanistic investigations and DFT calculations reveal insights into the reaction mechanism of the magnesium catalyzed protocol.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2019
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Article