Tunneling Controls the Reaction Pathway in the Deformylation of Aldehydes by a Nonheme Iron(III)-Hydroperoxo Complex: Hydrogen Atom Abstraction versus Nucleophilic Addition.

Bae, Seong Hee; Li, Xiao-Xi; Seo, Mi Sook; Lee, Yong-Min; Fukuzumi, Shunichi; Nam, Wonwoo

Bae, Seong Hee; Li, Xiao-Xi; Seo, Mi Sook; Lee, Yong-Min; Fukuzumi, Shunichi; Nam, Wonwoo.

Afiliação

Bae SH; Department of Chemistry and Nano Science , Ewha Womans University , Seoul 03760 , Korea.
Li XX; Department of Chemistry and Nano Science , Ewha Womans University , Seoul 03760 , Korea.
Seo MS; Department of Chemistry and Nano Science , Ewha Womans University , Seoul 03760 , Korea.
Lee YM; Department of Chemistry and Nano Science , Ewha Womans University , Seoul 03760 , Korea.
Fukuzumi S; Department of Chemistry and Nano Science , Ewha Womans University , Seoul 03760 , Korea.
Nam W; Faculty of Science and Engineering , Meijo University , SENTAN, Japan Science and Technology Agency (JST), Nagoya , Aichi 468-8502 , Japan.

J Am Chem Soc ; 141(19): 7675-7679, 2019 05 15.

Article em En | MEDLINE | ID: mdl-31034219

Assuntos

Aldeídos/química; Complexos de Coordenação/química; Hidrogênio/química; Ferro/química; Cinética; Temperatura

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Aldeídos / Complexos de Coordenação / Hidrogênio / Ferro Idioma: En Ano de publicação: 2019 Tipo de documento: Article

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