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A Multifunctional, Charge-Neutral, Chiral Octahedral M12 L12 Cage.
Boer, Stephanie A; White, Keith F; Slater, Benjamin; Emerson, Adrian J; Knowles, Gregory P; Donald, William A; Thornton, Aaron W; Ladewig, Bradley P; Bell, Toby D M; Hill, Matthew R; Chaffee, Alan L; Abrahams, Brendan F; Turner, David R.
Afiliação
  • Boer SA; School of Chemistry, Monash University, Clayton, VIC 3800, Australia.
  • White KF; School of Molecular Science, La Trobe University, Wodonga, VIC 3690, Australia.
  • Slater B; Barrer Centre, Department of Chemical Engineering, Imperial College London, SW7 2AZ, UK.
  • Emerson AJ; CSIRO, Private Bag 10, Clayton South MDC, VIC 3189, Australia.
  • Knowles GP; School of Chemistry, Monash University, Clayton, VIC 3800, Australia.
  • Donald WA; School of Chemistry, Monash University, Clayton, VIC 3800, Australia.
  • Thornton AW; School of Chemistry, University of New South Wales, Sydney, NSW, 2052, Australia.
  • Ladewig BP; CSIRO, Private Bag 10, Clayton South MDC, VIC 3189, Australia.
  • Bell TDM; Barrer Centre, Department of Chemical Engineering, Imperial College London, SW7 2AZ, UK.
  • Hill MR; Institute for Micro Process Engineering, Karlsruhe Institute of Technology, 76344, Eggenstein-Leopoldshafen, Germany.
  • Chaffee AL; School of Chemistry, Monash University, Clayton, VIC 3800, Australia.
  • Abrahams BF; CSIRO, Private Bag 10, Clayton South MDC, VIC 3189, Australia.
  • Turner DR; School of Chemical Engineering, Monash University, Clayton, VIC 3800, Australia.
Chemistry ; 25(36): 8489-8493, 2019 Jun 26.
Article em En | MEDLINE | ID: mdl-31056779
ABSTRACT
A chiral, octahedral M12 L12 cage, which is charge neutral and contains an internal void of about 2000 Å3 , is reported. The cage was synthesised as an enantiopure complex by virtue of amino-acid-based dicarboxylate ligands, which assemble around copper paddlewheels at the vertices of the octahedron. The cage persists in solution with retention of the fluorescence properties of the parent acid. The solid-state structure contains large pores both within and between the cages, and displays permanent porosity for the sorption of gases with retention of crystallinity. Initial tests show some enantioselectivity of the cage towards guests in solution.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article