Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst.
Chem Commun (Camb)
; 55(58): 8378-8381, 2019 Jul 25.
Article
em En
| MEDLINE
| ID: mdl-31233056
ABSTRACT
Regioselective C-H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin-heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2019
Tipo de documento:
Article