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Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst.
Teramae, Shota; Kito, Akane; Shingaki, Tomoteru; Hamaguchi, Yu; Yano, Yuuki; Nakayama, Takamori; Kobayashi, Yuko; Kato, Nobuki; Umezawa, Naoki; Hisamatsu, Yosuke; Nagano, Tetsuo; Higuchi, Tsunehiko.
Afiliação
  • Teramae S; Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Aichi 467-8603, Japan. higuchi@phar.nagoya-cu.ac.jp.
  • Kito A; Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Aichi 467-8603, Japan. higuchi@phar.nagoya-cu.ac.jp.
  • Shingaki T; Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
  • Hamaguchi Y; Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Aichi 467-8603, Japan. higuchi@phar.nagoya-cu.ac.jp.
  • Yano Y; Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Aichi 467-8603, Japan. higuchi@phar.nagoya-cu.ac.jp.
  • Nakayama T; Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Aichi 467-8603, Japan. higuchi@phar.nagoya-cu.ac.jp.
  • Kobayashi Y; Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Aichi 467-8603, Japan. higuchi@phar.nagoya-cu.ac.jp.
  • Kato N; Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Aichi 467-8603, Japan. higuchi@phar.nagoya-cu.ac.jp.
  • Umezawa N; Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Aichi 467-8603, Japan. higuchi@phar.nagoya-cu.ac.jp.
  • Hisamatsu Y; Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Aichi 467-8603, Japan. higuchi@phar.nagoya-cu.ac.jp.
  • Nagano T; Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
  • Higuchi T; Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Aichi 467-8603, Japan. higuchi@phar.nagoya-cu.ac.jp.
Chem Commun (Camb) ; 55(58): 8378-8381, 2019 Jul 25.
Article em En | MEDLINE | ID: mdl-31233056
ABSTRACT
Regioselective C-H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin-heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article