Bromine-Promoted Glycosidation of Conformationally Superarmed Thioglycosides.
Chemistry
; 25(51): 11831-11836, 2019 Sep 12.
Article
em En
| MEDLINE
| ID: mdl-31286579
ABSTRACT
Presented herein is a study of the conformation and reactivity of highly reactive thioglycoside donors. The structural studies have been conducted using NMR spectroscopy and computational methods. The reactivity of these donors has been investigated in bromine-promoted glycosylations of aliphatic and sugar alcohols. Swift reaction times, high yields, and respectable 1,2-cis stereoselectivity were observed in a majority of these glycosylations.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2019
Tipo de documento:
Article