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Generation and Reactivity of a One-Electron-Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand.
Shi, Huatian; Xie, Jianhui; Lam, William W Y; Man, Wai-Lun; Mak, Chi-Keung; Yiu, Shek-Man; Lee, Hung Kay; Lau, Tai-Chu.
Afiliação
  • Shi H; Department of Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong SAR, P. R. China.
  • Xie J; School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, 230009, P. R. China.
  • Lam WWY; Department of Food and Health Sciences, Technological and Higher Education Institute of Hong Kong, Tsing Yi Road, Hong Kong SAR, P. R. China.
  • Man WL; Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong SAR, P. R. China.
  • Mak CK; Department of Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong SAR, P. R. China.
  • Yiu SM; Department of Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong SAR, P. R. China.
  • Lee HK; Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China.
  • Lau TC; Department of Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong SAR, P. R. China.
Chemistry ; 25(56): 12895-12899, 2019 Oct 08.
Article em En | MEDLINE | ID: mdl-31325369
ABSTRACT
The synthesis and X-ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV (TAML)(N-Mes)]- (1), are reported. Compound 1 is oxidized by [(p-BrC6 H4 )3 N]+. [SbCl6 ]- and the resulting MnVI species readily undergoes H-atom transfer and nitrene transfer reactions.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article