Cooperative H2 Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an "Expanded PNNP Pincer" Ligand.
Chemistry
; 25(58): 13280-13284, 2019 Oct 17.
Article
em En
| MEDLINE
| ID: mdl-31424132
ABSTRACT
A naphthyridine-derived expanded pincer ligand is described that can host two copper(I) centers. The proton-responsive ligand can undergo reversible partial and full dearomatization of the naphthyridine core, which enables cooperative activation of H2 giving an unusual butterfly-shaped Cu4 H2 complex.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2019
Tipo de documento:
Article