Rhodium(I) Pincer Complexes of Nitrous Oxide.
Angew Chem Int Ed Engl
; 58(43): 15295-15298, 2019 Oct 21.
Article
em En
| MEDLINE
| ID: mdl-31513331
ABSTRACT
The synthesis of two well-defined rhodium(I) complexes of nitrous oxide (N2 O) is reported. These normally elusive adducts are stable in the solid state and persist in solution at ambient temperature, enabling comprehensive structural interrogation by 15 N NMR and IR spectroscopy, and single-crystal X-ray diffraction. These methods evidence coordination of N2 O through the terminal nitrogen atom in a linear fashion and are supplemented by a computational energy decomposition analysis, which provides further insights into the nature of the Rh-N2 O interaction.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2019
Tipo de documento:
Article