Synthesis of sulfur containing macrocycles with sucrose scaffold.
Carbohydr Res
; 486: 107825, 2019 Dec 01.
Article
em En
| MEDLINE
| ID: mdl-31580967
ABSTRACT
The first synthesis of sucrose-based macrocycles containing two sulfur atoms in the ring was presented. The synthesis was initiated from known 6,6'-dideoxy-6,6'-di-chloro-1',2,3,3',4,4'-hexa-O-benzyl-sucrose in which both terminal positions (C6 and C6') were elongated by the -S-CH2-CH2-OH unit. The resulting diol was converted into dichloride and reacted further with a series of diamines which afforded the corresponding macrocyclic derivatives in high yields.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Sacarose
/
Enxofre
/
Compostos Macrocíclicos
Idioma:
En
Ano de publicação:
2019
Tipo de documento:
Article