Fragmentation dynamics of nitrogen trifluoride induced by electron collision.
J Chem Phys
; 151(13): 134308, 2019 Oct 07.
Article
em En
| MEDLINE
| ID: mdl-31594329
ABSTRACT
The fragmentation dynamics of nitrogen trifluoride (NF3) in collisions with a 500 eV electron is studied by using a momentum imaging spectrometer. The kinetic energy releases of two-body, three-body, and four-body fragmentation channels of NF3 q+ (q = 2, 3) are investigated. The fragmentation dynamics of three-body, as well as four-body, dissociation channels is analyzed by the Dalitz plot and the Newton diagram. It is found that for all of the dissociation channels, the fragment including N atom (ion) always shares significant momenta, regardless of whether it is charged. For F atom, however, it is always emitted with negligible momenta.
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MEDLINE
Idioma:
En
Ano de publicação:
2019
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Article