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Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol.
Magnabosco, Giulia; Condorelli, Andrea M M; Rosenberg, Rose; Polishchuk, Iryna; Pokroy, Boaz; Gebauer, Denis; Cölfen, Helmut; Falini, Giuseppe.
Afiliação
  • Magnabosco G; Dipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum Università di Bologna, via F. Selmi 2, 40126 Bologna, Italy. Giuseppe.falini@unibo.it.
  • Condorelli AMM; Dipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum Università di Bologna, via F. Selmi 2, 40126 Bologna, Italy. Giuseppe.falini@unibo.it.
  • Rosenberg R; Department of Chemistry, Physical Chemistry, Universität Konstanz, Universitätsstraße 10, D-78457 Konstanz, Germany.
  • Polishchuk I; Department of Material Sciences, Technion-Israel Institute of Technology, 43000 Haifa, Israel.
  • Pokroy B; Department of Material Sciences, Technion-Israel Institute of Technology, 43000 Haifa, Israel.
  • Gebauer D; Department of Chemistry, Physical Chemistry, Universität Konstanz, Universitätsstraße 10, D-78457 Konstanz, Germany.
  • Cölfen H; Department of Chemistry, Physical Chemistry, Universität Konstanz, Universitätsstraße 10, D-78457 Konstanz, Germany.
  • Falini G; Dipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum Università di Bologna, via F. Selmi 2, 40126 Bologna, Italy. Giuseppe.falini@unibo.it.
Chem Commun (Camb) ; 55(86): 12944-12947, 2019 Oct 24.
Article em En | MEDLINE | ID: mdl-31599890
The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article