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Efficient Heterogeneous Palladium-Catalyzed Oxidative Cascade Reactions of Enallenols to Furan and Oxaborole Derivatives.
Li, Man-Bo; Posevins, Daniels; Geoffroy, Antoine; Zhu, Can; Bäckvall, Jan-E.
Afiliação
  • Li MB; Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.
  • Posevins D; Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601, P. R. China.
  • Geoffroy A; Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.
  • Zhu C; Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.
  • Bäckvall JE; Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.
Angew Chem Int Ed Engl ; 59(5): 1992-1996, 2020 Jan 27.
Article em En | MEDLINE | ID: mdl-31729824
ABSTRACT
A heterogeneous palladium-catalyzed oxidative cyclization of enallenols has been developed for the construction of highly substituted furan and oxaborole derivatives. The heterogeneous catalyst (Pd-AmP-MCF) exhibits high activity, high site- and stereoselectivity, and efficient palladium recyclability in the transformations.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article