Directing On-Surface Reaction Pathways via Metal-Organic Cu-N Coordination.
Chemphyschem
; 21(9): 843-846, 2020 May 05.
Article
em En
| MEDLINE
| ID: mdl-32096309
ABSTRACT
We demonstrate an enhancement of cyclization against polymerization for the on-surface debrominative coupling reaction, by using the metal-organic Cu-N coordination template to direct the reaction pathways. Experiments performed by using ultrahigh-vacuum scanning tunneling microscopy (UHV-STM), with the substitution of metal-coordination centers, metallic substrates and functional organic ligands, corroborate the template effect of the Cu-N coordination.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2020
Tipo de documento:
Article