Generation of Alkyl Radical through Direct Excitation of Boracene-Based Alkylborate.
J Am Chem Soc
; 142(22): 9938-9943, 2020 06 03.
Article
em En
| MEDLINE
| ID: mdl-32396733
ABSTRACT
The generation of tertiary, secondary, and primary alkyl radicals has been achieved by the direct visible-light excitation of a boracene-based alkylborate. This system is based on the photophysical properties of the organoboron molecule. The protocol is applicable to decyanoalkylation, Giese addition, and nickel-catalyzed carbon-carbon bond formations such as alkyl-aryl cross-coupling or vicinal alkylarylation of alkenes, enabling the introduction of various C(sp3) fragments to organic molecules.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2020
Tipo de documento:
Article