Denitrative Cross-Couplings of Nitrostyrenes.
Molecules
; 25(15)2020 Jul 27.
Article
em En
| MEDLINE
| ID: mdl-32726964
ABSTRACT
Interestingly, ß-nitrostyrenes, typically bench stable compounds, are highly promising cross-coupling partners, due to their excellent availability and well understood reactivity. In this review, we report on the discovery and advancements, in the field of stereoselective, denitrative cross-couplings of ß-nitrostyrenes with miscellaneous organic reagents. The rapidly expanding field offers alternative access to a broad range of functionalized alkenes, including ß-alkylated styrenes, chalcones, stilbenes, cinnamic acids, and conjugated sulfones and phosphonates. The most important mechanistic pathways are briefly discussed, to familiarize readers with the elementary reactions occurring during the coupling.
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Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Estirenos
/
Nitratos
Idioma:
En
Ano de publicação:
2020
Tipo de documento:
Article