CAESIUM RETENTION CHARACTERISTICS OF KNIFC-PAN RESIN FROM RIVER WATER.

ABSTRACT

The caesium retention characteristics of a potassium-nickel hexacyanoferrate resin in a polyacrylnitrile (KNiFC-PAN) matrix were tested in fresh water over the range of 2.5-400 mL min-1. The experimental setup used 2 mL resin and 4-L aliquots of freshwater samples. The results showed nearly 100% retention at speeds below 10 mL min-1, above 80% up to 100 mL min-1, and approached 50% at 400 mL min-1. Using 100 mL min-1 flow rate and KNiFC-PAN resin in a well-type HPGe detector, the minimum detectable concentration was reduced to 3 mBq kg-1 for 4-L aliquots of water samples from the previous 15 mBq kg-1 achieved by Powdex ion-exchange resin and a planar type HPGe detector.