Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation.
Inorg Chem
; 59(18): 13078-13090, 2020 Sep 21.
Article
em En
| MEDLINE
| ID: mdl-32902965
The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.
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Coleções:
01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2020
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Article