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Amino-Supported Palladium Catalyst for Chemo- and Stereoselective Domino Reactions.
Li, Man-Bo; Yang, Jie; Yang, Ying; Xu, Guo-Yong; Luo, Gen; Yang, Jianping; Bäckvall, Jan-E.
Afiliação
  • Li MB; Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601, P. R. China.
  • Yang J; Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-10691, Stockholm, Sweden.
  • Yang Y; Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601, P. R. China.
  • Xu GY; Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601, P. R. China.
  • Luo G; Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601, P. R. China.
  • Yang J; School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, P. R. China.
  • Bäckvall JE; Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-10691, Stockholm, Sweden.
Angew Chem Int Ed Engl ; 60(2): 670-674, 2021 Jan 11.
Article em En | MEDLINE | ID: mdl-32969105
A solid amino-supported palladium catalyst is used in an oxidative domino reaction for the diastereoselective construction of alkyne-substituted cyclopentenol compounds. This heterogeneous catalyst exhibits high efficiency and excellent chemoselectivity, as well as good recyclability. The chemoselectivity of the domino reactions was readily controlled by switching the solvent and catalyst. Asymmetric syntheses and an oxidative carbocyclization-borylation reaction have also been developed based on the heterogeneous palladium catalyst.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article