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Oxide of lanthanoids can catalyse non-oxidative propane dehydrogenation: mechanistic concept and application potential of Eu2O3- or Gd2O3-based catalysts.
Perechodjuk, Anna; Kondratenko, Vita A; Lund, Henrik; Rockstroh, Nils; Kondratenko, Evgenii V.
Afiliação
  • Perechodjuk A; Leibniz-Institut für Katalyse e.V., Albert-Einstein-Str. 29a, Rostock, 18059, Germany. Evgenii.kondratenko@catalysis.de.
  • Kondratenko VA; Leibniz-Institut für Katalyse e.V., Albert-Einstein-Str. 29a, Rostock, 18059, Germany. Evgenii.kondratenko@catalysis.de.
  • Lund H; Leibniz-Institut für Katalyse e.V., Albert-Einstein-Str. 29a, Rostock, 18059, Germany. Evgenii.kondratenko@catalysis.de.
  • Rockstroh N; Leibniz-Institut für Katalyse e.V., Albert-Einstein-Str. 29a, Rostock, 18059, Germany. Evgenii.kondratenko@catalysis.de.
  • Kondratenko EV; Leibniz-Institut für Katalyse e.V., Albert-Einstein-Str. 29a, Rostock, 18059, Germany. Evgenii.kondratenko@catalysis.de.
Chem Commun (Camb) ; 56(85): 13021-13024, 2020 Oct 27.
Article em En | MEDLINE | ID: mdl-33000811
This paper demonstrates the potential of Eu2O3 and Gd2O3 as catalysts for non-oxidative propane dehydrogenation to propene. They reveal a higher activity than the state-of-the-art bare ZrO2-based catalysts due to the higher intrinsic activity of Gdcus or Eucus in comparison with that of Zrcus (cus = coordinatively unsaturated).

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article