Atom economical coupling of benzophenone and N-heterocyclic aromatics with SmI2.
Chem Commun (Camb)
; 56(79): 11875-11878, 2020 Oct 11.
Article
em En
| MEDLINE
| ID: mdl-33021260
ABSTRACT
The use of stoechiometric SmI2 in combination with benzophenone and N-heterocyclic aromatics such as bipyridine, phenanthroline and pyridine allows the direct ortho-coupling of both partners in an atom economical reaction free of any other coupling additives. The transformation was investigated by 1H NMR, X-ray studies and theoretical calculations providing reaction intermediates and the reaction mechanism.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Tipo de estudo:
Health_economic_evaluation
Idioma:
En
Ano de publicação:
2020
Tipo de documento:
Article