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π-Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons.
Martínez-Abadía, Marta; Strutynski, Karol; Lerma-Berlanga, Belén; Stoppiello, Craig T; Khlobystov, Andrei N; Martí-Gastaldo, Carlos; Saeki, Akinori; Melle-Franco, Manuel; Mateo-Alonso, Aurelio.
Afiliação
  • Martínez-Abadía M; POLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, 20018, Donostia-San Sebastian, Spain.
  • Strutynski K; CICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193, Aveiro, Portugal.
  • Lerma-Berlanga B; Instituto de Ciencia Molecular, Universidad de Valencia, 46980, Paterna, Spain.
  • Stoppiello CT; School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
  • Khlobystov AN; The Nanoscale and Microscale Research Centre, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
  • Martí-Gastaldo C; School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
  • Saeki A; The Nanoscale and Microscale Research Centre, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
  • Melle-Franco M; Instituto de Ciencia Molecular, Universidad de Valencia, 46980, Paterna, Spain.
  • Mateo-Alonso A; Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan.
Angew Chem Int Ed Engl ; 60(18): 9941-9946, 2021 Apr 26.
Article em En | MEDLINE | ID: mdl-33555658
ABSTRACT
Three-dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic (D3d ) nodes. Such 3D COFs are six-fold interpenetrated as the result of interframework π-stacking, which enable charge transport properties that are not expected for 3D COFs.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article