Stable Thermotropic 3D and 2D Double Gyroid Nanostructures with Sub-2-nm Feature Size from Scalable Sugar-Polyolefin Conjugates.
Angew Chem Int Ed Engl
; 60(16): 8710-8716, 2021 04 12.
Article
em En
| MEDLINE
| ID: mdl-33567131
ABSTRACT
Ultra-low molecular weight disaccharide-polyolefin conjugates with cellobiose, lactose and maltose head groups and atactic polypropene tails, such as 1, undergo a series of irreversible thermotropic order-order transitions with increasing temperature to provide nanostructured phases in the sequence lamellar (L), hexagonal perforated lamellar (HPL), double gyroid (DG) and hexagonal cylindrical (C). The DG phase displays exceptional stability at ambient temperature and features two interpenetrating sugar domain networks having a sub-2-nm strut width and a lattice parameter, aDG , of 13.1â
nm. The unique stability of this DG phase extends further within ultrathin films all the way down to the two-dimensional limit of 15â
nm in which film thickness, l, is now less than the surface-oriented unit cell height, hDG . In addition to raising the fundamental question of what minimally constitutes a Schoen triply periodic minimal surface and DG lattice, these results serve to establish the class of sugar-polyolefin conjugates as a new material platform for nanoscience and nanotechnology.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2021
Tipo de documento:
Article