Synthesis of 4,5-Benzotropone π Complexes of Iron, Rhodium, and Iridium and Their Potential Use in Catalytic Borrowing-Hydrogen Reactions.
Inorg Chem
; 60(7): 4332-4336, 2021 Apr 05.
Article
em En
| MEDLINE
| ID: mdl-33769049
ABSTRACT
The syntheses of rhodium, iridium, and iron π complexes bearing 4,5-benzotropone ligands are reported. X-ray crystallographic analyses revealed that a tropone core coordinates to a metal center in a η4 manner with a tub-form geometry. Some of the benzotropone π complexes exhibited catalytic activity for N-alkylation of aniline by borrowing hydrogen.
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Coleções:
01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2021
Tipo de documento:
Article