Catalytic Asymmetric Synthesis of Silicon-Stereogenic Dihydrodibenzosilines: Silicon Central-to-Axial Chirality Relay.

Guo, Yonghong; Liu, Meng-Meng; Zhu, Xujiang; Zhu, Liru; He, Chuan

Guo, Yonghong; Liu, Meng-Meng; Zhu, Xujiang; Zhu, Liru; He, Chuan.

Afiliação

Guo Y; Shenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, Guangdong, 518055, China.
Liu MM; Shenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, Guangdong, 518055, China.
Zhu X; Shenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, Guangdong, 518055, China.
Zhu L; Shenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, Guangdong, 518055, China.
He C; Shenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, Guangdong, 518055, China.

Angew Chem Int Ed Engl ; 60(25): 13887-13891, 2021 Jun 14.

Article em En | MEDLINE | ID: mdl-33830619

Palavras-chave

axial chirality; chirality relay; enantioselective C−H silylation; silicon-central chirality; silicon-stereogenic monohydrosilanes

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article