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Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra.
Wang, Heng; Wang, Kun; Xu, Yaping; Wang, Wu; Chen, Shaohua; Hart, Matthew; Wojtas, Lukasz; Zhou, Li-Peng; Gan, Lin; Yan, Xuzhou; Li, Yiming; Lee, Juhoon; Ke, Xian-Sheng; Wang, Xu-Qing; Zhang, Chang-Wei; Zhou, Shasha; Zhai, Tianyou; Yang, Hai-Bo; Wang, Ming; He, Jiaqing; Sun, Qing-Fu; Xu, Bingqian; Jiao, Yang; Stang, Peter J; Sessler, Jonathan L; Li, Xiaopeng.
Afiliação
  • Wang H; College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong 518060, China.
  • Wang K; Shenzhen University General Hospital, Shenzhen University Clinical Medical Academy, Shenzhen, Guangdong 518055, China.
  • Xu Y; Departments of Physics and Astronomy & Chemistry, Mississippi State University, Mississippi State, Mississippi 39762, United States.
  • Wang W; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin 130012, China.
  • Chen S; Department of Physics, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China.
  • Hart M; School for Engineering of Matter, Transport and Energy, Arizona State University, Tempe, Arizona 85287, United States.
  • Wojtas L; School for Engineering of Matter, Transport and Energy, Arizona State University, Tempe, Arizona 85287, United States.
  • Zhou LP; Department of Chemistry, University of South Florida, Tampa, Florida 33620, United States.
  • Gan L; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China.
  • Yan X; State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, China.
  • Li Y; School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240, China.
  • Lee J; Department of Chemistry, University of South Florida, Tampa, Florida 33620, United States.
  • Ke XS; Department of Chemistry, The University of Texas, Austin, Texas 78712, United States.
  • Wang XQ; Department of Chemistry, The University of Texas, Austin, Texas 78712, United States.
  • Zhang CW; Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China.
  • Zhou S; Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China.
  • Zhai T; State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, China.
  • Yang HB; State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, China.
  • Wang M; Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China.
  • He J; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin 130012, China.
  • Sun QF; Department of Physics, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China.
  • Xu B; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China.
  • Jiao Y; College of Engineering and Nanoscale Science and Engineering Center, University of Georgia, Athens, Georgia 30602, United States.
  • Stang PJ; School for Engineering of Matter, Transport and Energy, Arizona State University, Tempe, Arizona 85287, United States.
  • Sessler JL; Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, United States.
  • Li X; Department of Chemistry, The University of Texas, Austin, Texas 78712, United States.
J Am Chem Soc ; 143(15): 5826-5835, 2021 04 21.
Article em En | MEDLINE | ID: mdl-33848163
Parastichy, the spiral arrangement of plant organs, is an example of the long-range apparent order seen in biological systems. These ordered arrangements provide scientists with both an aesthetic challenge and a mathematical inspiration. Synthetic efforts to replicate the regularity of parastichy may allow for molecular-scale control over particle arrangement processes. Here we report the packing of a supramolecular truncated cuboctahedron (TCO) into double-helical (DH) nanowires on a graphite surface with a non-natural parastichy pattern ascribed to the symmetry of the TCOs and interactions between TCOs. Such a study is expected to advance our understanding of the design inputs needed to create complex, but precisely controlled, hierarchical materials. It is also one of the few reported helical packing structures based on Platonic or Archimedean solids since the discovery of the Boerdijk-Coxeter helix. As such, it may provide experimental support for studies of packing theory at the molecular level.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Substâncias Macromoleculares / Nanofios Tipo de estudo: Health_economic_evaluation Idioma: En Ano de publicação: 2021 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Substâncias Macromoleculares / Nanofios Tipo de estudo: Health_economic_evaluation Idioma: En Ano de publicação: 2021 Tipo de documento: Article