Redox-Active Tin Metal-Organic Framework with a Thiolate-Based Ligand.
Inorg Chem
; 60(17): 12691-12695, 2021 Sep 06.
Article
em En
| MEDLINE
| ID: mdl-34402610
ABSTRACT
Metal-organic frameworks (MOFs) and coordination polymers composed of thiolates as coordinating functional groups are interesting materials with unique optical and electronical properties. Herein, we report the preparation of KGF-4 and KGF-10, two Sn-MOF crystal structures with bonds between Sn and thiolate. KGF-10 was isolated as a pure phase and found to exhibit redox properties and a semiconducting band structure, as confirmed by first-principles (density functional theory) calculations.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2021
Tipo de documento:
Article