Same knot, longer rope: altering ligand geometry provides control over nuclearity in self-assembled trefoil knots.
Chem Commun (Camb)
; 57(76): 9772-9775, 2021 Sep 23.
Article
em En
| MEDLINE
| ID: mdl-34486610
ABSTRACT
Taking advantage of the accumulation of a number of noncovalent intramolecular interactions, octanuclear and hexanuclear trefoil knots are self-assembled based on half-sandwich rhodium fragments. The selective synthesis of either the octanuclear or hexanuclear knot can be controlled by altering different dipyridyl arms.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2021
Tipo de documento:
Article