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Copper(II)-mediated C-H sulphenylation or selenylation of tryptophan enabling macrocyclization of peptides.
Kobayashi, Daishiro; Kohmura, Yutaka; Hayashi, Junya; Denda, Masaya; Tsuchiya, Koichiro; Otaka, Akira.
Afiliação
  • Kobayashi D; Institute of Biomedical Sciences and Graduate School of Pharmaceutical Sciences, Tokushima University, Sho-machi, 1-78-1, Tokushima 770-8505, Japan. aotaka@tokushima-u.ac.jp.
  • Kohmura Y; Institute of Biomedical Sciences and Graduate School of Pharmaceutical Sciences, Tokushima University, Sho-machi, 1-78-1, Tokushima 770-8505, Japan. aotaka@tokushima-u.ac.jp.
  • Hayashi J; Institute of Biomedical Sciences and Graduate School of Pharmaceutical Sciences, Tokushima University, Sho-machi, 1-78-1, Tokushima 770-8505, Japan. aotaka@tokushima-u.ac.jp.
  • Denda M; Institute of Biomedical Sciences and Graduate School of Pharmaceutical Sciences, Tokushima University, Sho-machi, 1-78-1, Tokushima 770-8505, Japan. aotaka@tokushima-u.ac.jp.
  • Tsuchiya K; Institute of Biomedical Sciences and Graduate School of Pharmaceutical Sciences, Tokushima University, Sho-machi, 1-78-1, Tokushima 770-8505, Japan. aotaka@tokushima-u.ac.jp.
  • Otaka A; Institute of Biomedical Sciences and Graduate School of Pharmaceutical Sciences, Tokushima University, Sho-machi, 1-78-1, Tokushima 770-8505, Japan. aotaka@tokushima-u.ac.jp.
Chem Commun (Camb) ; 57(82): 10763-10766, 2021 Oct 14.
Article em En | MEDLINE | ID: mdl-34585682
Cu(II)-mediated C-H sulphenylation or selenylation of Trp indole by a derivative of cysteine or selenocysteine enables access to the tryptathionine unit or its selenium congener. The mechanism of these protocols, which allow macrocyclization of Trp-containing peptides, has been studied.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Peptídeos Cíclicos / Selênio / Triptofano / Cobre Idioma: En Ano de publicação: 2021 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Peptídeos Cíclicos / Selênio / Triptofano / Cobre Idioma: En Ano de publicação: 2021 Tipo de documento: Article