Engineering In-Plane Nickel Phosphide Heterointerfaces with Interfacial sp HP Hybridization for Highly Efficient and Durable Hydrogen Evolution at 2 A cm-2.
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; 18(4): e2105642, 2022 Jan.
Article
em En
| MEDLINE
| ID: mdl-34825490
ABSTRACT
The catalytic hydrogen-evolving activities of transition-metal phosphides are greatly related to the phosphorus content, but the physical origin of performance enhancement remains ambiguous, and tuning the catalytic activity of nickel phosphides (NiP2 /Ni5 P4 ) remains challenging due to unfavorable H* adsorption. Here, a strategy is introduced to integrate P-rich NiP2 and P-poor Ni5 P4 into in-plane heterostructures by anion substitution, in which P atoms at the in-plane interfaces perform as active sites to adsorb H* and thus facilitate the hydrogen evolution reaction (HER) process via modulating the electronic structure between NiP2 and Ni5 P4 . Consequently, the NiP2 /Ni5 P4 hybrid exhibits an outstanding hydrogen-evolving activity, requiring only 30 and 76 mV to afford 10 and 100 mA cm-2 in acid, respectively. It surpasses most of the earth-abundant electrocatalysts thus far, and is comparable to Pt catalysts (30/72 mV at 10/100 mA cm-2 ). Particularly, it can run smoothly at large current density and only requires 247 mV to reach 2000 mA cm-2 . Detailed theoretical calculations reveal that its exceptional activity stems from the moderate overlap of density states between P 2p and H 1s orbitals, thus optimizing the H*-adsorption strength. This work highlights a new avenue toward the fabrication of robust non-noble electrocatalysts by constructing in-plane heterojunctions.
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01-internacional
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MEDLINE
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En
Ano de publicação:
2022
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Article