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Heterobimetallic uranyl(VI) alkoxides of lanthanoids: formation through simple ligand exchange.
Grödler, Dennis; Weidemann, Martin L; Lichtenberg, Andreas; Greven, Tobias; Nickstadt, Robin; Haydo, Malek; Wickleder, Mathias; Klein, Axel; Johrendt, Dirk; Mathur, Sanjay; Zegke, Markus; Raauf, Aida.
Afiliação
  • Grödler D; Department of Chemistry, Institute for Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne, Germany. m.zegke@uni-koeln.de.
  • Weidemann ML; Department of Chemistry, Ludwig-Maximilians-University of Munich, Butenandtstraße 5-13 (D), 81377 Munich, Germany.
  • Lichtenberg A; Department of Chemistry, Institute for Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne, Germany. m.zegke@uni-koeln.de.
  • Greven T; Department of Chemistry, Institute for Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne, Germany. m.zegke@uni-koeln.de.
  • Nickstadt R; Department of Chemistry, Institute for Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne, Germany. m.zegke@uni-koeln.de.
  • Haydo M; Department of Chemistry, Institute for Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne, Germany. m.zegke@uni-koeln.de.
  • Wickleder M; Department of Chemistry, Institute for Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne, Germany. m.zegke@uni-koeln.de.
  • Klein A; Department of Chemistry, Institute for Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne, Germany. m.zegke@uni-koeln.de.
  • Johrendt D; Department of Chemistry, Ludwig-Maximilians-University of Munich, Butenandtstraße 5-13 (D), 81377 Munich, Germany.
  • Mathur S; Department of Chemistry, Institute for Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne, Germany. m.zegke@uni-koeln.de.
  • Zegke M; Department of Chemistry, Institute for Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne, Germany. m.zegke@uni-koeln.de.
  • Raauf A; Department of Chemistry, Institute for Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne, Germany. m.zegke@uni-koeln.de.
Chem Commun (Camb) ; 58(6): 835-838, 2022 Jan 18.
Article em En | MEDLINE | ID: mdl-34931647
ABSTRACT
Lanthanoid and actinoid silylamides are versatile starting materials. Herein we show how a simple ligand exchange with tert-butanol leads to the formation of the first trimeric heterobimetallic uranyl(VI)-lanthanoid(III) alkoxide complexes. The µ3 coordination of the endogenous uranyl oxo atom results in a significant elongation of the bond length and a significant deviation from the linear uranyl arrangement.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article