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Thioether-directed Rh(III)-catalyzed peri-selective acyloxylation of arenes.
Xie, Hui; Song, Jia-Lin; Jiang, Chun-Yong; Huang, Yan-Xia; Zeng, Jun-Yi; Liu, Xu-Ge; Zhang, Shang-Shi; Yang, Fan.
Afiliação
  • Xie H; Center for Drug Research and Development, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China. zhangshangshi@gdpu.edu.cn.
  • Song JL; Center for Drug Research and Development, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China. zhangshangshi@gdpu.edu.cn.
  • Jiang CY; School of Ethnic Medicine, Guizhou Minzu University, Guiyang, 550025, P. R. China.
  • Huang YX; Center for Drug Research and Development, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China. zhangshangshi@gdpu.edu.cn.
  • Zeng JY; Center for Drug Research and Development, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China. zhangshangshi@gdpu.edu.cn.
  • Liu XG; Key Laboratory of Brain Targeted Nanodrugs of Henan Province, School of Pharmacy, Henan University, Kaifeng, Henan 475004, P. R. China. liuxg7@henu.edu.cn.
  • Zhang SS; Center for Drug Research and Development, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China. zhangshangshi@gdpu.edu.cn.
  • Yang F; Center for Drug Research and Development, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China. zhangshangshi@gdpu.edu.cn.
Org Biomol Chem ; 20(3): 565-569, 2022 01 19.
Article em En | MEDLINE | ID: mdl-34985096
ABSTRACT
A thioether directed acyloxylation of arenes has been realized via Cp*Rh(III)-catalyzed C-H activation and subsequent coupling with carboxylic acids. This new method showed high functional group compatibility and broad substrate scope. Primary mechanistic studies have been conducted and a tentative reaction mechanism was proposed. It represents the first example of a thioether-directed Cp*Rh(III)-catalyzed C(sp2)-H acyloxylation reaction.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article