Thioether-directed Rh(III)-catalyzed peri-selective acyloxylation of arenes.
Org Biomol Chem
; 20(3): 565-569, 2022 01 19.
Article
em En
| MEDLINE
| ID: mdl-34985096
ABSTRACT
A thioether directed acyloxylation of arenes has been realized via Cp*Rh(III)-catalyzed C-H activation and subsequent coupling with carboxylic acids. This new method showed high functional group compatibility and broad substrate scope. Primary mechanistic studies have been conducted and a tentative reaction mechanism was proposed. It represents the first example of a thioether-directed Cp*Rh(III)-catalyzed C(sp2)-H acyloxylation reaction.
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Coleções:
01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article