Nitrile Synthesis via Desulfonylative-Smiles Rearrangement.
J Org Chem
; 87(6): 4460-4467, 2022 03 18.
Article
em En
| MEDLINE
| ID: mdl-35229594
ABSTRACT
Herein, we designed a simple nitrile synthesis from N-[(2-nitrophenyl)sulfonyl]benzamides via base-promoted intramolecular nucleophilic aromatic substitution. The process features redox-neutral conditions as well as no requirement of toxic cyanide species and transition metals. Our process shows broad scope and various functional group compatibility, affording a variety of (hetero)aromatic nitriles in good to excellent yields.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Elementos de Transição
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article