Cooperative approaches in catalytic hydrogenation and dehydrogenation.
Chem Soc Rev
; 51(6): 1881-1898, 2022 Mar 21.
Article
em En
| MEDLINE
| ID: mdl-35230366
ABSTRACT
Metal-ligand cooperativity (MLC) is an established strategy for developing effective hydrogenation and dehydrogenation catalysts. Metal-metal cooperativity (MMC) in bimetallic complexes is not as well understood, and to date has had limited implementation in (de)hydrogenation. Herein we use (de)hydrogenation processes as a platform to examine modes of cooperativity, with a particular focus on catalytic mechanisms. We investigate how lessons learnt from the extensive development of metal-ligand cooperative catalysts can aid the ongoing development of metal-metal cooperative catalysts.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Hidrogenação
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article