Fe3O4 hard templating to assemble highly wrinkled graphene sheets into hierarchical porous film for compact capacitive energy storage.
RSC Adv
; 9(35): 20107-20112, 2019 Jun 25.
Article
em En
| MEDLINE
| ID: mdl-35514724
ABSTRACT
Highly wrinkled graphene film (HWGF) with high packing density was synthesized by combining an electrostatically self-assembling process, a vacuum filtration-induced film assembling process and capillary compression. Fe3O4 nanoparticles were used as a low-cost and environment-friendly hard template. Hierarchical porosity and high packing density were achieved with the aid of capillary compression in the presence of Fe3O4 nanoparticles. This strategy enables integration of highly wrinkled graphene sheets to form highly compact carbon electrodes with a continuous ion transport network. The generated HWGF exhibited a high packing density of 1.53 g cm-3, a high specific surface area of 383 m2 g-1 and a hierarchically porous structure. The HWGF delivered a high capacitance of 242 F g-1 and 370 F cm-3 at 0.2 A g-1 in 6 M KOH aqueous electrolyte system with excellent rate capability (202 F g-1 and 309 F cm-3 retained at 20 A g-1). The capacity retention rate reached 97% after 10 000 cycles at 1 A g-1. The HWGF-based supercapacitor exhibited a high energy density of 17 W h kg-1 at the power density of 49 W kg-1. Such high capacitive performances could be attributed to the highly dense but porous graphene assemblies composed of highly wrinkled graphene sheets.
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01-internacional
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MEDLINE
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En
Ano de publicação:
2019
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Article