Au-based bimetallic catalysts: how the synergy between two metals affects their catalytic activity.

ABSTRACT

Supported bimetallic nanoparticles are particularly attractive catalysts due to increased activity and stability compared to their monometallic counterparts. In this work, gold-based catalysts have been studied as catalysts for the selective base-free oxidation of glucose. TiO2-supported Au-Pd and Au-Cu series prepared by the sol-immobilization and precipitation-reduction methods, respectively, showed a significant synergistic effect, particularly when the theoretical weight ratio of the two metals was close to 1 1 (with an actual experimental bulk Au/Pd molar ratio of ca. 0.8 and ca. 0.4 for Au/Cu) in both cases. XPS analysis showed that the presence of Au δ+, Pd2+ and CuOH species played an important role in the base-free glucose oxidation.