Rhodium(II)-Catalyzed C(sp3 )-H Diamination of Arylcyclobutanes.
Angew Chem Int Ed Engl
; 61(30): e202205493, 2022 07 25.
Article
em En
| MEDLINE
| ID: mdl-35606340
ABSTRACT
Activated by multiple consecutive oxidative radical-polar crossover and desaturation processes, the selective diamination of arylcyclobutanes, which is difficult to perform by classical metallonitrene C-H insertion, was achieved in a short time by rhodium(II) catalysis using N-fluorobenzenesulfonimide (NFSI) as the oxidant and nitrogen source.
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01-internacional
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MEDLINE
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Ródio
Idioma:
En
Ano de publicação:
2022
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Article