In Situ Water-Compatible Polymer Entrapment: A Strategy for Transferring Superhydrophobic Microporous Organic Polymers to Water.

ABSTRACT

Microporous organic polymer nanoparticles bearing tetraphenylethylene moieties (MOPTs) were prepared in the presence of poly(vinylpyrrolidone) (PVP). The PVP was entrapped into the microporous network of MOPT to form MOPT-P and played the roles of size control, porosity enhancement, and surface property management. MOPT materials without PVP showed superhydrophobicity with a water contact angle of 151°. In comparison, the MOPT-P showed excellent water compatibility. Moreover, due to the aggregation-induced emission property of tetraphenylethylene moieties, the MOPT-P showed emission and excellent emission-based sensing of nitrophenols in water with Ksv values in the range of 1.26 × 104 ∼ 3.37 × 104 M-1. It is noteworthy that the MOPT-P used water only as a sensing medium and did not require additional organic solvents to enhance water dispersibility of materials. The MOPT-P could be recovered and reused for the sensing at least five times.