Pd-Catalyzed Selective B(6)-H Phosphorization of nido-Carboranes via Cascade Deboronation/B-H Activation from closo-Carboranes.
Inorg Chem
; 61(25): 9623-9630, 2022 Jun 27.
Article
em En
| MEDLINE
| ID: mdl-35700190
ABSTRACT
Efficient Pd-catalyzed regioselective B(6)-H phosphorization of nido-carboranes via cascade deboronation/B-H activation of readily available C-substituted o-carboranes with various phosphines using 3-methylpyridine or isoquinoline as a directing group in combination with pyridine ligands has been developed, affording unprecedented B(6)-phosphinated nido-carborane derivatives with high selectivity in a simple one-pot process.
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MEDLINE
Idioma:
En
Ano de publicação:
2022
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Article