Recycling of Solvent Allows for Multiple Rounds of Reproducible Nanoparticle Synthesis.
J Am Chem Soc
; 144(26): 11646-11655, 2022 07 06.
Article
em En
| MEDLINE
| ID: mdl-35737471
ABSTRACT
Metal nanoparticles have superior properties for a variety of applications. In many cases, the improved performance of metal nanoparticles is tightly correlated with their size and atomic composition. To date, colloidal synthesis is the most commonly used technique to produce metal nanoparticles. However, colloidal synthesis is currently a laboratory scale technique that has not been applied at larger scales. One of the greatest challenges facing large-scale colloidal synthesis of metal nanoparticles is the large volume of long-chain hydrocarbon solvents and surfactants needed for the synthesis, which can dominate the cost of nanoparticle production. In this work, we demonstrate a protocol, based on solvent distillation, which enables the reuse of colloidal nanoparticle synthesis surfactants and solvents for over 10 rounds of successive syntheses and demonstrates that pure solvents and surfactants are not necessarily needed to produce uniform nanocrystals. We show that this protocol can be applied to the production of a wide variety of mono- and bimetallic nanoparticles with reproducible sizes and compositions, which leads to reproducible performance as heterogeneous catalysts. A techno-economic assessment demonstrates the potential of this technique to greatly reduce the solvent-related costs of colloidal metal nanoparticle synthesis, which could contribute to its wider application at commercial scale.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Nanopartículas Metálicas
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article