Bioenhanced Rapid Redox Initiation for RAFT Polymerization in the Air.
Macromol Rapid Commun
; 43(19): e2200218, 2022 Oct.
Article
em En
| MEDLINE
| ID: mdl-35751146
ABSTRACT
A well-controlled bioenhanced reversible addition-fragmentation chain transfer (RAFT) in the presence of air is carried out by using glucose oxidase (GOx), glucose, ascorbic acid (Asc acid), and ppm level of hemin. The catalytic concentration of hemin is employed to enhance hydrogen peroxide (H2 O2 )/Asc acid redox initiation, achieving rapid RAFT polymerization. Narrow molecular weight distributions and high monomer conversion (Ð as low as 1.09 at >95% conversion) are achieved within tens of minutes. Several kinds of monomers are used to verify the universal implication of the presented method. The influences of the pH and feed ratio of each component on the polymerization rate are assessed. Besides, a polymerization rate regulation is realized by managing Asc acid addition. This work significantly increases the rate of redox-initiated GOx-deoxygen RAFT polymerization by using simple and green reactants, facilitating the application of RAFT polymerization in areas such as biomedical applications.
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Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Glucose Oxidase
/
Peróxido de Hidrogênio
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article