Oxygen vacancy triggering the broad-spectrum photocatalysis of bismuth oxyhalide solid solution for ciprofloxacin removal.

ABSTRACT

The construction of a broad-spectrum photocatalytic system is of great significance for maximizing the utilization of solar energy. Herein, a surface oxygen vacancy triggering high-efficient broad-spectrum BiOCl0.5I0.5 solid solution photocatalyst was successfully fabricated via a one-pot solvothermal process. The UV-vis diffuse reflectance spectra revealed that the introduced oxygen vacancy appears to extend the absorption region of BiOCl0.5I0.5 to a wider wavelength range. Under λ > 580 nm light irradiation for 5 h, nearly 85.6% ciprofloxacin was degraded by BiOCl0.5I0.5 with rich oxygen vacancy, the ciprofloxacin removal efficiency was 3.4 times higher than that with less oxygen vacancy. Moreover, the density functional theory calculations and photoelectrochemical characterizations indicated the excited electrons would preferentially transfer to the new defect level induced by oxygen vacancy, thus greatly reducing the recombination of photogenerated carriers. This work tends to deepen the understanding of defect engineering in steering the construction of broad-spectrum Bi-based solid solution photocatalysts as well as its application in environmental remediation.