Controlling Electronic Events Through Rational Structural Design in Subphthalocyanine-Corrole Dyads: Synthesis, Characterization, and Photophysical Properties.
Chemistry
; 28(60): e202201552, 2022 Oct 26.
Article
em En
| MEDLINE
| ID: mdl-35862831
ABSTRACT
Porphyrinoids are considered perfect candidates for their incorporation into electron donor-acceptor (D-A) arrays due to their remarkable optoelectronic properties and low reorganization energies. For the first time, a series of subphthalocyanine (SubPc) and corrole (Cor) were covalently connected through a short-range linkage. SubPc axial substitution strategies were employed, which allowed the synthesis of the target molecules in decent yields. In this context, a qualitative synthetic approach was performed to reverse the expected direction of the different electronic events. Consequently, in-depth absorption, fluorescence, and electrochemical assays enabled the study of electronic and photophysical properties. Charge separation was observed in cases of electron-donating Cors, whereas a quantitative energy transfer from the Cor to the SubPc was detected in the case of electron accepting Cors.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Porfirinas
Tipo de estudo:
Qualitative_research
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article